In a large skillet, heat oil and butter over medium heat for 2 minutes.
Add sliced onions and minced garlic, saute' stirring constantly for 5 minutes.
Add pork chops, brown on both sides, 10 minutes per side.
Remove chops to a serving plate, set aside.
Pour water into skillet, stirring constantly, loosen browned bits from the bottom of pan.
Stir can of condensed cream of mushroom soup into water in skillet, stirring constantly.
Return pork chops to skillet, reduce heat to medium low. Cover, simmer gently for 1 hour.
Meanwhile, prepare five grains blend.
In a medium saucepan combine water and grains.
Bring to a boil; reduce heat to low, cover and cook for 10 minutes.
For softer grains, cook 2 to 3 minutes longer.
Remove from heat, let stand, covered, for 5 minutes.
Drain any excess water, fluff with a fork and season to taste.